Download Advances in Nitrogen Heterocycles, Volume 3 by Moody C.J. PDF
By Moody C.J.
This quantity incorporates a diversity of themes resembling the activation and manipulation of pyrroles, the synthesis of annelated pyrroles utilizing acylation reactions and the synthesis of kainoids, a family members of hugely biologically energetic nitrogen heterocycles.
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Extra resources for Advances in Nitrogen Heterocycles, Volume 3
C~ D. Pyrrolo[ 1,2-a]indoles . . . . . . . . . . . E. 7-Aminoaziridinomitosenes . . . . . . . . . Acknowledgments .......................... Reference and Notes . . . . . . . . . . . . . 83. Copyright 9 1998 by JAI Press Inc. All rights of reproduction in any form reserved. ISBN: 0-7623-0209-7 45 ...... 46 46 46 47 49 49 60 63 67 71 77 77 46 ERIC D. EDSTROM I. INTRODUCTION The efficient and regioselective synthesis of substituted pyrrole tings continues to be an important goal in organic synthesis.
For examples of Diels-Alder reactions with vinylpyrroles, see: (a) Jones, R. ; Saliente, T. ; Arques, J. S. J. Chem. Soc. Perkin Trans. 11984, 2541. (b) Jones, R. ; Arques, J. S. Tetrahedron 1981, 37, 1597. (c) Jones, R. ; Marriot, M. T. ; Rosenthal, W. ; Arques, J. J. Org. Chem. 1980, 45, 4515. (d) Muchowski, J. ; Scheller, M. E. Tetrahedron Lett. 1987, 28, 3453. ; Wocadlo, S. Tetrahedron Lett. 1994, 35, 7923. 44 L. MARK HODGES and W. DEAN HARMAN 24. For recent reports and reviews on the synthesis of indoles using palladium, see: (a) Fagnola, M.
Myers, W. ; Harman, W. D. J. Org. Chem. 1995, 60, 2125. 13. (a) Hodges, L. ; Moody, M. ; Harman, W. J. Am. Chem. Soc. 1994,116, 7931. (b) Hodges, L. ; Spera, M. U; Moody, M. ; Harman, W. D. J. Am. Chem. Soc. 1996, 118, 7117. 14. ; Koontz, J. ; Hodges, L. ; Nilsson, K. ; Neely, L. ; Myers, W. ; Harman, W. D. J. Am. Chem. Soc. 1995, 117, 3405. 15. The pentaammineosmium(II) metal center also binds in a dihapto fashion to several other classes of aromatic molecules, including benzenes, naphthalenes, phenols, anisoles, anilines, furans, and thiophenes, activating them toward further functionalization.